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Publications: Selected Publications

Selected Publications | Patents

Selected Publications from more than 120 technical papers

  1. K.T. Rim, D. Eom, L. Liu, E. Stolyarova, J.M. Raitano, S.-W. Chan, M. Flytzani-Stephanopoulos, G. W. Flynn, "Charging and Chemical Reactivity of Gold Nanoparticles and Adatoms on the (111) Surface of Single-Crystal Magnetite: A Scanning Tunneling Microscopy/Spectroscopy Study," J. Phys. Chem. C, 113: 10198-10205 (2009).
  2. L.F. Allard, A. Borisevich, W. Deng, R. Si, M. Flytzani-Stephanopoulos, S.H. Overbury, "Evolution of gold structure during thermal treatment of Au/FeOx catalysts revealed by aberration-corrected electron microscopy," J. Electron Microscopy, 58:199-212 (2009)
  3. X. She, M. Flytzani-Stephanopoulos, C. Wang, Y. Yang, C.H.F. Peden, "SO2 -induced stability of Ag-alumina catalysts in the SCR of NO with methane," Applied Catalysis B: Environmental, 88:98-105 (2009).
  4. W. Deng, A.I. Frenkel, R. Si, M. Flytzani-Stephanopoulos, "Reaction-relevant gold structures in the low temperature water-gas shift reaction on Au-CeO2 ," J. Phys. Chem. C (2008) 112:12834-12840.
  5. Z. Zhou, M. Flytzani-Stephanopoulos, S. Kooi, H. Saltsburg, "The Role of the Interface in CO Oxidation on Au/CeO2 Multi-layer Nanotowers," Advanced Functional Materials (2008) 18: 2801-2807.
  6. R. Si and M. Flytzani-Stephanopoulos, "Shape and Crystal Plane Effect of Nanoscale Ceria on the Activity of Au-CeO2 Catalysts for the Water-Gas Shift Reaction," Angewandte Chemie International Edition 47:2884-2887 (2008).
  7. D. Pierre, W. Deng and M. Flytzani-Stephanopoulos, "The Importance of Strongly Bound Pt-CeOx Species for the Water-gas Shift Reaction: Catalyst Activity and Stability Evaluation," Topics in Catalysis 46: 363-373 (2007).
  8. W. Deng, C. Carpenter, N. Yi, and M. Flytzani-Stephanopoulos, "Comparison of the activity of Au/CeO2 and Au/Fe2O3 catalysts for the CO oxidation and the water-gas shift reactions" Invited paper. Topics in Catalysis 44:199-208 (2007).
  9. X. She and M. Flytzani-Stephanopoulos, "Activity and stability of Ag-alumina for the selective catalytic reduction of NOx with methane in high-content SO2 gas streams," Catalysis Today 127: 207-218 (2007).
  10. F.C. Meunier, D. Reid, A. Goguet, S. Shekhtman, C. Hardacre, R. Burch, W. Deng and M. Flytzani-Stephanopoulos, "Quantitative analysis of the reactivity of formate species seen by DRIFTS over a Au/Ce(La)O2 water–gas shift catalyst: First unambiguous evidence of the minority role of formates as reaction intermediates" Journal of Catalysis 247: 269-79 (2007).
  11. M. Manzoli, F. Boccuzzi, A. Chiorino, F. Vindigni, W. Deng, and M. Flytzani-Stephanopoulos, "Spectroscopic features and reactivity of CO adsorbed on different Au/CeO2 catalysts," Journal of Catalysis 245: 308-15 (2007).
  12. M. Flytzani-Stephanopoulos, M. Sakbodin, Z. Wang. "Regenerative adsorption and removal of H2S from hot fuel gas streams by rare earth oxides." Science 312: 1508-10 (2006).
  13. W. Deng and M. Flytzani-Stephanopoulos, "On the deactivation of nanostructured gold-ceria and platinum-ceria catalysts for the water-gas shift reaction in practical fuel cell applications", Angewandte Chemie International Edition 45: 2285-2289 (2006).
  14. X. She and M. Flytzani-Stephanopoulos, "The role of Ag-O-Al species in silver-alumina catalysts for the selective catalytic reduction of NOX with methane" J. Catalysis 237, 79-93 (2006).
  15. Q. Fu, W. Deng, H. Saltsburg and M. Flytzani-Stephanopoulos, "Activity and stability of low-content gold-ceria catalysts for the water-gas shift reaction", invited paper, Appl. Catal. B 56 (1-2), 57-68 (2005).
  16. Z. Wang and M. Flytzani-Stephanopoulos, "Cerium Oxide Based Sorbents for Regenerative Hot Reformate Gas Desulfurization", Energy and Fuels 19, 2089-2097 (2005).
  17. W. Deng, J. DeJesus, H. Saltsburg and M. Flytzani-Stephanopoulos; "Low-content gold-ceria catalysts for the water-gas shift and preferential CO oxidation reactions", Appl. Catal. A 291 (1-2), 126-135 (2005).
  18. X. Qi and M. Flytzani-Stephanopoulos, "Activity and stability of Cu-CeO2 catalysts in high-temperature water-gas shift for fuel cell applications", invited paper, Ind. & Eng. Chem. Res., 43, 3055-3062 (2004).
  19. M. Flytzani-Stephanopoulos, "Water gas -shift with integrated H2-separation process" Final Report to DOE/NETL, Grant # DE-FG2600NT40819 (March 2004).
  20. Y Liu, Q. Fu and M. Flytzani-Stephanopoulos, "Preferential oxidation of CO in H2 over CuO-CeO2 catalysts", Catalysis Today, 93-95, 241-246 (2004).
  21. Q. Fu, H. Saltsburg, and M. Flytzani-Stephanopoulos, "Active non-metallic Au and Pt Species on Ceria-based Water-gas shift Catalysts", Science 301, 935-938 (2003).
  22. M. Flytzani-Stephanopoulos and W. Liu, "Sulfur Oxides Removal-heterogeneous", invited chapter, Encyclopedia of Catalysis, J. Wiley & Sons, 2002.
  23. M. Kobayashi and M. Flytzani-Stephanopoulos, "Reduction and Sulfidation Kinetics of Cerium Oxide and Cu-modified Cerium Oxide", Ind. Eng. Chem. Res., 41 (13), 3115-3123 (2002).
  24. P. Ciambelli, D. Sannino, M. C. Gaudino, M. Flytzani-Stephanopoulos, "Ag and Co Exchanged Ferrierite in Lean NOx Abatement with CH4". Stud. Surf. Sci. Catal., 142 (B), 1031 (2002).
  25. M. Flytzani-Stephanopoulos, "Nanostructured Cerium Oxide Ecocatalysts", invited article, MRS Bulletin, 885-889, Nov. 2001.
  26. L. F. Cordoba, M. Flytzani-Stephanopoulos and C. Montes de Correa, "Lean NOx Reduction with Dodecane over Cerium and Palladium Loaded Mordenite," Appl. Catal. B: Environmental 33, 25-33 (2001).
  27. Q. Fu, A. Weber and M. Flytzani-Stephanopoulos, "Nanostructured Au-CeO2 Catalysts for Low-Temperature Water-Gas Shift Reaction," Catal. Letters 77 (1/3) 87-95 (2001).
  28. T. Zhu and M. Flytzani-Stephanopoulos, "Catalytic Partial Oxidation of Methane to Synthesis Gas Over Ni-CeO2," Applied Catalysis A: 208, 403-417 (2001).
  29. M. Flytzani-Stephanopoulos and T. Zhu, "Catalytic Recovery of Elemental Sulfur from Sulfur Dioxide-Laden Gas Streams," invited chapter, in Green Engineering: ACS Symposium Series 766, Chapter 14, 174-191 (2000).
  30. M. Flytzani-Stephanopoulos, T. Zhu and Y. Li, "Ceria-based Catalysts for the Recovery of Elemental Sulfur from SO2-laden Gas Streams," Catalysis Today 62, 145-158 (2000).
  31. A Keshavaraja, X. She, and M. Flytzani-Stephanopoulos, "Selective Catalytic Reduction of NO with CH4 over Ag-alumina catalysts," Appl. Catal. B, 27, L1-L9 (2000).
  32. Y Li, Q. Fu and M. Flytzani-Stephanopoulos, "Low-Temperature Water-Gas Shift Reaction over Cu- and Ni-loaded Cerium Oxide Catalysts," Appl. Catal. B: 27, 179-191 (2000).
  33. Z. Li and M. Flytzani-Stephanopoulos, "Effects of Water Vapor and Sulfur Dioxide on the Performance of Ce-Ag-ZSM-5 for the SCR of NO with CH4," Appl. Catal. B, 22, 35-47 (1999).
  34. Lj. Kundakovic and M. Flytzani-Stephanopoulos, "Deep Oxidation of Methane over Zirconia-Supported Ag Catalysts," Appl. Catal. A: General 183, 35-51 (1999).
  35. T. Zhu, Lj. Kundakovic, A. Dreher and M. Flytzani-Stephanopoulos, "Redox Chemistry Over CeO2-Based Catalysts: SO2 Reduction by CO or CH4," invited paper, Catal. Today, 50, 381-397 (1999).
  36. Z. Li and M. Flytzani-Stephanopoulos, "On the Promotion of Ag-ZSM-5 by Cerium for the SCR of NO by Methane," J. Catal. 182, 313-327 (1999).
  37. T. Zhu, A. Dreher and M. Flytzani-Stephanopoulos, "Direct Reduction of SO2 to Elemental Sulfur by Methane Over Ceria-Based Catalysts," Appl. Catal. B: Environmental 21, 103-120 (1999).
  38. Lj. Kundakovic and M. Flytzani-Stephanopoulos, "Cu- and Ag- Modified Cerium Oxide Catalysts for Methane Oxidation," J. Catal. 179, 203-221 (1998).
  39. Lj. Kundakovic and M. Flytzani-Stephanopoulos, "Reduction Characteristics of Copper Oxide in Cerium and Zirconium Oxide Systems," Appl. Catal. A: General 171, 13-29 (1998).
  40. Z. Li and M. Flytzani-Stephanopoulos, "Kinetics of Sulfidation Reactions between H2S and Bulk Oxide Sorbents," Invited review paper, NATO - Advanced Study Institute on "Desulfurization of Hot Coal Gas with Regenerable Metal Oxide Sorbents: New Developments," Kusadasi, Turkey, July 7-19, 1996, (A.T. Atimtay and D.P. Harrison, eds.), vol. G 42, Springer Verlag, 1998, pp 179-211.
  41. M. Flytzani-Stephanopoulos, W. Liu, T. Zhu, and L. Kundakovic, "Elemental Sulfur Recovery from SO2-Rich Streams," Invited review paper, NATO - Advanced Study Institute on "Desulfurization of Hot Coal Gas with Regenerable Metal Oxide Sorbents: New Developments," Kusadasi, Turkey, July 7-19, 1996, (A.T. Atimtay and D.P. Harrison, eds.), vol. G 42, Springer Verlag, 1998, pp 365-383.
  42. Z. Li and M. Flytzani-Stephanopoulos, "Selective Catalytic Reduction of Nitric Oxide by Methane over Cerium and Silver Ion-Exchanged ZSM-5," Appl. Catal. A: General 165, 15-34 (1997).
  43. Z. Li and M. Flytzani-Stephanopoulos, "Cu-Cr-O and Cu-Ce-O Regenerable Oxide Sorbents for Hot Gas Desulfurization," Ind. & Eng. Chem. Res. 36, 187-196, (1997).
  44. W. Liu and M. Flytzani-Stephanopoulos, "Transition Metal-Promoted Oxidation Catalysis by Fluorite Oxides: A Study of Carbon Monoxide Oxidation over Cu-CeO2," Chemical Engineering Journal, 64, 283-294 (1996).
  45. W. Liu and M. Flytzani-Stephanopoulos, "Transition Metal/Fluorite Oxides as Active Catalysts for the Reduction of Sulfur Dioxide to Elemental Sulfur by Carbon Monoxide," Catalysis Today 28 (4), 391-403 (1996).
  46. A.S.Tschoepe, W. Liu, M. Flytzani-Stephanopoulos and J.Y. Ying, "Redox Activity of Non-stoichiometric Cerium Oxide-based Nanocrystalline Catalysts," J. Catal. 157, 42-50 (1995).
  47. C.W. Krueger, S. Patnaik, C.A. Wang and M. Flytzani-Stephanopoulos, "CH3I Vapor Etching of GaAs in a Vertical Rotating Disk Reactor", J. Crystal Growth 169, 51-60 (1996).
  48. Y Zhang and M. Flytzani-Stephanopoulos, "Hydrothermal Stability of Cerium Modified Cu-ZSM-5 Catalyst for Nitric Oxide Decomposition," J. Catal. 164, 131-145 (1996).
  49. W. Liu and M. Flytzani-Stephanopoulos, "Total Oxidation of Carbon Monoxide and Methane over Transition Metal-Fluorite Oxide Composite Catalysts I. Catalyst Composition and Activity," J. Catal. 153, 304-316 (1995).
  50. W. Liu and M. Flytzani-Stephanopoulos, "Total Oxidation of Carbon Monoxide and Methane over Transition Metal-Fluorite Oxide Composite Catalysts II. Catalyst Characterization and Kinetics," J. Catal. 153, 317-332 (1995).
  51. Y Zhang, K. Leo, A.F. Sarofim, Z. Hu, and M. Flytzani-Stephanopoulos, "Preparation Effects on the Activity of Cu-ZSM-5 Catalysts for NO Decomposition", Catal. Lett. 31, 75-89 (1995).
  52. Y Zhang, T. Sun, A.F. Sarofim, and M. Flytzani-Stephanopoulos, "Decomposition of Nitric Oxide over Metal- Modified Cu -ZSM- 5 Catalysts," ACS Symposium Series 587, "Reduction of Nitrogen Oxide Emissions", ed. by U.S. Ozkan, S.K. Agarwal and G. Marcelin, Ch. 11, pp. 133-146 (1995).
  53. C.W. Krueger, C.A. Wang, D. Hsieh, and M. Flytzani-Stephanopoulos, "CH3I VaporEtching of Masked and Patterned GaAs", J. Crystal Growth 153, 81-89 (1995).
  54. W. Liu, A.F. Sarofim, M. Flytzani-Stephanopoulos, "Reduction of Sulfur Dioxide over Metal Oxide Composite Catalysts." Appl. Catal. B: Environ. 4: 167-186 (1994).
  55. W. Liu, A.F. Sarofim, and M. Flytzani-Stephanopoulos, "Complete Oxidation of Carbon Monoxide and Methane over Metal- Promoted Fluorite Oxide Catalysts," Chem. Eng. Sci. 49 (No. 24A), 4871-4888 (1994).
  56. S. Lew, A.F. Sarofim, M. Flytzani-Stephanopoulos, "Modeling of the Sulfidation of Zinc-Titanium Oxide Sorbents with Hydrogen Sulfide," AIChE J. 38, 1161-1169 (1992).
  57. S. Lew, A.F. Sarofim, M. Flytzani-Stephanopoulos, "The Sulfidation of Zinc Titanate and Zinc Oxide Solids," Ind. Eng. Chem. Res. 31, 1890-1899 (1992).
  58. S. Lew, A.F. Sarofim, M. Flytzani-Stephanopoulos, "The Reduction of Zinc Titanate and Zinc Oxide-Solids," Chem. Eng. Sci. 47, 1421-1431 (1992).
  59. C. Krueger, C.A. Wang, and M. Flytzani-Stephanopoulos, "Dry Chemical Etching of GaAs," Appl. Phys. Lett. 60, 1459-1461 (1992).
  60. C. Krueger, C.A. Wang, R.A. Brown, and M. Flytzani-Stephanopoulos, "OMVPE Regrowth of CH3I-Vapor-Etched GaAs," JEM 21, 299-304 (1992).
  61. A.F. Sarofim, L. Tognotti, H. Kopsinis, M. Stoukides, "Incineration of Contaminated Soils in an Electrodynamic Balance," ACS Symposium Series 468, ed. by W. Tedder and F.G. Pohland, Ch. 3, pp. 29-49 (1991).
  62. L. Tognotti, M. Flytzani-Stephanopoulos, A.F. Sarofim, H. Kopsinis, and M. Stoukides, "Study of Adsorption-Desorption of Contaminants on Single Soil Particles Using the Electrodynamic Thermogravimetric Analyzer," Environ. Sci. Technol. 25, 104-109 (1991).
  63. V. Patrick, G.R. Gavalas, K. Jothimurugesan, M. Flytzani-Stephanopoulos, "High Temperature Sulfidation – Regeneration of CuO-Al2O3 Sorbents," Ind. Eng. Chem. Res. 28, 931 (1989)
  64. S. Lew, K. Jothimurugesan, M. Flytzani-Stephanopoulos, "High Temperature H2S Removal from Fuel Gases by Regenerable Zinc Oxide-Titanium Dioxide Sorbents," Ind. Eng. Chem. Res. 28, 535-541 (1989)
  65. M. Bagajewicz, S.S. Tamhankar, M.F. Stephanopoulos, and G.R. Gavalas, "Hydrogen Sulfide Removal by Supported Vanadium Oxide," Environ. Sci. and Technol. 22, 467-470 (1988).
  66. G.R. Gavalas, S. Edelstein, M. Flytzani-Stephanopoulos and T.A. Weston, "Alkali-Alumina Sorbents for High-Temperature Removal of SO2," AIChE J. 33, 258-266 (1987).
  67. M. Flytzani-Stephanopoulos, G.E. Voecks and T. Charng, "Modeling of Heat Transfer in Non-Adiabatic Monolith Reactors and Experimental Comparisons of Metal Monoliths with Packed Beds," Chem. Eng. Sci. 41, 1203 (1986).
  68. S. S. Tamhankar, M. Bagajewicz, G. R. Gavalas, P. K. Sharma, and M. Flytzani-Stephanopoulos, "Mixed-Oxide Sorbents for High-Temperature Removal of H2S," Ind. Eng. Chem. Proc. Des. Dev. 25, 429-437 (1986).
  69. G.E. Voecks and M. Flytzani-Stephanopoulos, "Autothermal Reforming of Aliphatic and Aromatic Hydrocarbon Liquids," Int. J. Hydrogen Energy 8, 539 (1983).
  70. G.E. Voecks and M. Flytzani-Stephanopoulos, "Catalytic Autothermal Reforming Increases Fuel Cell Flexibility," Energy Progress 1, 52 (1981).
  71. M. Flytzani-Stephanopoulos, L.D. Schmidt, and R. Caretta, "Steady-State and Transient Oscillations in NH3 Oxidation on Pt," J. Catalysis, 64, 346 (1980).
  72. M. Flytzani-Stephanopoulos and L.D. Schmidt, "Morphology and Etching Processes on Macroscopic Metal Catalysts," invited review paper, Progress in Surface Science 9, 83-111 (1979).
  73. M. Flytzani-Stephanopoulos and L.D. Schmidt, "Morphologies of PT Catalyst Surfaces," Chem. Eng. Sci. 34, 365-72, (1979).
  74. M. Flytzani-Stephanopoulos, S. Wong, and L.D. Schmidt "Surface Morphology of Platinum Catalysts," J. Catalysis 49, 51 (1977).
  75. M. Flytzani-Stephanopoulos, K.E. Gubbins, C.G. Gray, "Thermodynamics of Mixtures of Non-Spherical Molecules II. Strong Polar, Quadrupolar, and Overlap Forces," Mol. Phys. 30, 1649-76 (1975).
 
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