graphic 4 Colby Street, Tufts University, Medford, MA 02155 | Phone: (617) 627-3900 | Fax: (617) 627-3991
  graphic Biomimetic Devices Lab  


Research conducted at the Tufts Nano-CEL aims at applying principles of heterogeneous catalysis to the solution of problems in the production of hydrogen and green chemicals.

A major research effort is in the area of catalytic hydrogen production reactions; e.g. fuel conversion to synthesis gas; steam reforming of hydrocarbons and alcohols; and the water-gas shift reaction. Effective catalysts for these reactions are highly dispersed metals (Au, Pt, Pd, Cu) on certain oxide supports. We investigate the catalyst structure-activity relationships in these systems by following specific metal structures (atoms, clusters, particles) and their activity and stability on selected oxides; and by evaluating the potential shape and crystal plane effect of oxides through careful preparation of the latter at the nanoscale according to novel synthesis techniques.

An important reaction in all fuel conversions is the water-gas shift reaction used to upgrade hydrogen gas streams. We have recently demonstrated that the active sites for this reaction are single-atoms bound to various supports through -O, and this holds true for [Au-Ox-], [Pt-Ox-}, [Cu-Ox-], etc.. The supports serve as dispersants of the active sites, but do not participate in the reaction pathway, other than to supply ľOH, which is regenerated by facile H2O dissociation. The oxide structure and its defects control the dispersion of atom sites, and hence the overall catalytic activity. Similar findings were reported for alcohol dehydrogenation and steam reforming reactions. To study these atomic-scale interactions, controlled synthesis techniques are used, as well as advanced characterization techniques to follow the structural evolution of the catalyst in situ as a function of the reaction conditions.

Another area of research is that of selective hydrogenation and dehydrogenation reactions using single atom alloys. These are alloys of a selective but low-activity metal like Cu with small amounts of an active but non selective metal like Pd or Pt, the latter present as atoms embedded in the surface of Cu. The new catalysts are bifunctional, H2 dissociation taking place on the Pd or Pt, spillover to Cu, where the reaction takes place. This was demonstrated for the selective hydrogenation of alkynes and alkadienes both SAAs of Pt or Pd/Cu(111) and on Cu nanoparticle supported on silica or alumina.

Work at the NanoCEL also supports research underway at the IMASC (Integrated Mesoscale Architectures for Sustainable Catalysis), a DOE Energy Frontier Research Center (EFRC) directed by Prof. Cynthia Friend, Harvard University. Information about the IMASC center's activities >

  Tufts seal

© Tufts University | Privacy