The Rybak-Akimova Group

  1. O.V. Makhlynets, W.N. Oloo, Y.S. Moroz, I.G. Belaya, T.D. Palluccio, A.S. Filatov, P. Müller, M.A. Cranswick, L. Que, Jr., E.V. Rybak-Akimova. H2O2 activation with biomimetic non-haem iron complexes and AcOH: Connecting the g = 2.7 EPR signal with a visible chromophore. Chem. Commun., 2014, 50, 645-648.
  2. G. Yang, B.C. Noll, E.V. Rybak-Akimova. (2R,2’S—2,2’-Bipiperidine-1,1’-diium dibromide. Acta Cryst. E., 2013, 69(11), o1711.
  3. T.D. Palluccio, E.V. Rybak-Akimova, S. Majumdar, X. Cai, M. Chui, M. Temprado, J.S. Silvia, A.F. Cozzolino, D. Tofan, A. Velian, C.C. Cummins, B. Captain, C.D. Hoff. Thermodynamic and kinetic study of cleavage of the N-O bond of N-oxides by a vanadium(III) complex: Enhanced oxygen atom transfer reaction rates for adducts of nitrous oxide and mesityl nitrile oxide. J. Am. Chem. Soc., 2013, 135, 11357-11372.
  4. D. Kumar, R. Latifi, S. Kumar, E.V. Rybak-Akimova, M.A. Sainna, S.P. de Visser. Rationalization of the barrier height for the p-Z-styrene epoxidation by iron(IV)-oxo porphyrin cation radicals with variable axial ligands. Inorg. Chem., 2013, 52, 7968-7979.
  5. M.K. Coggins, X. Sun, Y. Kwak, E.I. Solomon, E. Rybak-Akimova, J. A. Kovacs. Characterization of metastable intermediates formed in the reaction between a Mn(II) complex and dioxygen, including a crystallographic structure of a binuclear Mn(III)-peroxo species. J. Am. Chem. Soc., 2013, 135, 5631-5640. Featured in the JACS-IC Virtual Issue on metalloenzyme models.
  6. J. Frisch, R. McDonnell, E.V. Rybak-Akimova, L. Que, Jr. Factors affecting the carboxylate shift upon formation of nonheme diiron-O2 adducts. Inorg. Chem., 2013, 52, 2627-2636.
  7. R. Latifi, M.A. Sainna, E.V. Rybak-Akimova, S.P. de Visser. Does hydrogen-bonding donation to manganese(IV)-oxo and iron(IV)-oxo oxidants affect the oxygen-atom transfer ability? A computational study. Chem. Eur. J., 2013, 19, 4058-4068.
  8. X. Sun, S.V. Kryatov, E.V. Rybak-Akimova. Kinetic insights into the reactivity of the intermediates generated from hydrogen peroxide and diiron(III) complex with tris(picolyl)amine (TPA). Dalton Trans., 2013, 42, 4427-4435.
  9. A.F. Cozzolino, D. Tofan, C.C. Cummins, M. Temprado, T.D. Palluccio, E.V. Rybak-Akimova, S. Majumdar, X. Cai, B. Captain, C.D. Hoff. Two-step binding of O2 to vanadium(III) tris-anilide complex to form a non-vanadyl vanadium(V) peroxo complex. J. Am. Chem. Soc., 2012, 134, 18249 -18252.
  10. M.S. Kryatova, O.V. Makhlynets, A.Y. Nazarenko, E.V. Rybak-Akimova. Nickel(II) complexes with tetradentate N4 ligands: Synthesis, structure, electrochemistry, and thermochromism in solution. Inorg. Chim. Acta, 2012, 387, 74-80.
  11. W. Ye, R.J. Staples, E.V. Rybak-Akimova. Oxygen atom transfer mediated by an Fe(IV)/Fe(II) macrocyclic complex containing pyridine and tertiary amine donors. J. Inorg. Biochem., 2012, 115, 1-12.
  12. W. Ye, D.M. Ho, S. Friedle, T.D. Palluccio, E.V. Rybak-Akimova. Role of Fe(IV)-oxo intermediates in stoichiometric and catalytic oxidations mediated by iron pyridine-azamacrocycles. Inorg. Chem., 2012, 51, 5006-5021.
  13. E.A. Mikhalyova, O.V.Makhlynets, T.D. Palluccio, A.S. Filatov, E.V. Rybak-Akimova. New efficient iron catalyst for olefin epoxidation with hydrogen peroxide. Chem. Commun., 2012, 48, 687-689.
  14. L.C. Gregor, G.T. Rowe, E.V. Rybak-Akimova, J.P. Caradonna. Mechanistic investigation of cyclohexane oxidation by a binuclear non-heme iron model complex: Evidence of product inhibition by low-temperature UV-vis stopped-flow spectroscopic kinetic studies. Dalton Trans., 2012, 41, 777-782.
  15. Y.S. Moroz, M.K. Takase, P. Müller, E.V. Rybak-Akimova. N1,N2,N3-Tris((2,6-dimethylphenyl)amino)ethyl)amine. Acta Cryst. E, 2011, 67(Pt 12), o3421.
  16. Y.S. Moroz, A.F. Cozzolino, E.V. Rybak-Akimova, C.C. Cummins. Bis(µ222-2,4,6-trimethylbenzonitrile)bis[(N-isopropyl-3,5-dimethylanilido)-molybdenum)](Mo—Mo). Acta Cryst., 2011, E67, m1643-m1644.
  17. D. Huang, O. V. Makhlynets, L.L. Tan, S.C. Lee, Elena V. Rybak-Akimova, R.H. Holm. Fast carbon dioxide fixation by 2,6-pyridinecarboxamidato-nickel(II)-hydroxide complexes: Influence of changes in reactive site environment on reaction rates. Inorg. Chem., 2011, 50(20), 10070-10081.
  18. X. Cai, S. Majumdar, G. C. Fortman, L.M. Frutos, M. Temprado, C.R. Clough, C.C. Cummins, M.E. Germain, T. Palluccio, E.V. Rybak-Akimova, B. Captain, C.D. Hoff. Thermodynamic, kinetic, and mechanistic study of oxygen atom transfer from mesityl nitrile oxide to phosphines and to a terminal metal phosphido complex. Inorg. Chem., 2011, 50(19), 9620-9630.
  19. T.R. Dugan, X. Sun, E.V. Rybak-Akimova, O.O. Olayinka, T.R. Cundari, P.L. Holland. A masked two-coordinate cobalt(I) complex that activates C-F bonds. J. Am. Chem. Soc., 2011, 133(32), 12418-12421.
  20. D. Huang, O. V. Makhlynets, L.L. Tan, S.C. Lee, Elena V. Rybak-Akimova, R.H. Holm. Kinetics and mechanistic analysis of an extremely rapid carbon dioxide fixation reaction. Proc. Natl. Acad. Sci. USA, 2011, 108(4), 1222–1227.
  21. L. M. Berreau, T. Borowski, K. Grubel, C. J. Allpress, J. P. Wikstrom, M. E. Germain, E. V. Rybak-Akimova, D. L. Tierney. Mechanistic studies of the O2-dependent aliphatic carbon−carbon bond cleavage reaction of a nickel enolate complex. Inorg. Chem., 2011, 50 (3), 1047-1057.
  22. X. Cai, S. Majumdar, G. C. Fortman, C. S. J. Cazin, A. M. Z. Slawin, C. Lhermitte, R. Prabhakar, M. E. Germain, T. Palluccio, S. P. Nolan, E. V. Rybak-Akimova, M. Temprado, B. Captain, C. D. Hoff. Oxygen binding to [Pd(L)(L′)] (L= NHC, L′ = NHC or PR3, NHC = N-heterocyclic carbene). Synthesis and structure of a paramagnetic trans-[Pd(NHC)21-O2)2] complex. J. Am. Chem. Soc., 2011, 133(5), 1290-1293. Featured in Chemical and Engineering News.
  23. O.V. Makhlynets, E.V. Rybak-Akimova. Aromatic hydroxylation at a non-heme iron center: observed intermediates and insights into the nature of the active species. Chem. Eur. J., 2010, 47, 13995-14006. Recognized as a very important article and featured on the cover.
  24. R. Roesner, E.V. Rybak-Akimova. Preface. Coord. Chem. Rev., 2010, 254, 1589-1592.
  25. Guest Editor, Coordination Chemistry Reviews, Special Issue honoring Daryle H. Busch (more than 20 contributions; published in 2010).
  26. E.V. Rybak-Akimova. Mechanisms of Oxygen Binding and Activation at Transition Metal Centers. Chapter 4 in "Physical Inorganic Chemistry", Vol. 2 (A. Bakac, Editor). Wiley, 2010, pp. 109-188.
  27. J.P. Wikstrom, A.S. Filatov, R.J. Staples, C.R. Guifarro, E.V. Rybak-Akimova. Steric and counterion effects on the structure of dipicolylamine nickel complexes. Inorg. Chim. Acta, 2010, 363, 884-890.
  28. J.P. Wikstrom, A.S. Filatov, E.A. Mikhalyova, M. Shatruk, B.M. Foxman, E.V. Rybak-Akimova. Carbonate formation within a nickel dimer: Synthesis of coordinatively unsaturated bis(μ-hydroxo) dinickel complex and its reactivity toward carbon dioxide. Dalton Trans., 2010, 39, 2504-2514.
  29. J.P. Wikstrom, A.S. Filatov, E.V. Rybak-Akimova. Condensation of nitriles with amides promoted by coordinatively unsaturated bis-nickel(II)-hydroxy complex: A new route to alkyl- and aryl-imidoylamidines. Chem. Commun., 2010, 46, 424-426.
  30. O.V. Makhlynets, P. Das, S. Taktak, M. Flook, R. Mas-Ballesté, E.V. Rybak-Akimova, L. Que, Jr. Iron-promoted ortho- and/or ipso-hydroxylation of benzoic acids with H2O2. Chem. Eur. J., 2009, 15, 13171-13180.
  31. M.E. Germain, M. Temprado, A. Castonguay, O.P. Kryatova, E.V. Rybak-Akimova, J.J. Curley, A. Mendiratta, Y.-C. Tsai, C.C. Cummins, P. Rajeev, J.E. McDonough, C.D. Hoff. Coordination-mode control of bound nitrile radical complex reactivity: Intercepting end-on nitrile-Mo(III) radicals at low temperature. J. Am. Chem. Soc., 2009, 131, 15412-15423.
  32. V.G. Organo, A.S. Filatov, J.S. Quartararo, Z.M. Friedman, E.V. Rybak-Akimova. Nickel(II) complexes of monofunctionalized pyridine-azamacrocycles: Synthesis, structures, pendant arm "on-off" coordination equilibria, and peroxidase-like activity. Inorg. Chem., 2009, 48, 8456-8468.
  33. L.V. Penkova, A. Masiag, E.V. Rybak-Akimova, M. Haukka, V.A. Pavlenko, S.T. Iskenderov, H. Kozlowski, F. Meyer, I.O. Fritsky. Efficient catalytic phosphate ester cleavage by binuclear zinc(II) pyrazolate complexes as functional models of metallophosphatases. Inorg. Chem., 2009, 48, 6960-6971.
  34. V.G. Organo, W. Ye, P.K. Agarwal, E.V. Rybak-Akimova. Biotinylation of aminopyridine-based macrocycles and metallomacrocycles and inclusion of biotinylated iron(II) complex in avidin. J. Incl. Phenom. Macrocyclic Chem., 2009, 64, 15-21.
  35. J.Y. Yang, S.-Y. Liu, I.V. Korendovych, E.V. Rybak-Akimova, D.G. Nocera, Hangman salen platforms containing dibenzofuran scaffolds. ChemSusChem, 2008, 1, 941-949.
  36. G.T. Rowe, E.V. Rybak-Akimova, J.P. Caradonna. Heterolytic cleavage of peroxide by a diferrous compound generates metal-based intermediates identical to those observed with reactions utilizing oxygen-atom-donor molecules. Chem Eur. J., 2008, 14, 8303-8311.
  37. M. Temprado, J.E. McDonough, A. Mendiratta, Y.-C. Tsai, G.C. Fortman, C.C. Cummins, E.V. Rybak-Akimova, C.D. Hoff. Thermodynamic and kinetic studies of H atom transfer from HMo(CO)35-C5H5) to Mo(N[t-Bu]Ar)3 and (PhCN)Mo(N[t-Bu]Ar)3: Direct insertion of benzonitrile into the Mo-H bond of HMo(N[t-Bu]Ar)3 forming (Ph(H)C=N)Mo(N[t-Bu]Ar)3. Inorg. Chem., 2008, 47, 9380-9389.
  38. E.V. Rybak-Akimova, O.E. Voronina, J. Wikstrom. Metal-Containing Compounds on Carbon Nanotubes. In Chemistry of Carbon Nanotubes (V. Basiuk and E. Basiuk, Eds.). American Scientific Publishers: Los Angeles, CA, 2008, Volume 2, Chapter 18, pp. 82-108.
  39. Company, A., Palavicini, S., Garcia-Bosch, I., Mas-Baleste, R., Que Jr., L., Rybak-Akimova, E.V., Casella, L., Ribas, X., Costas, M. Tyrosinase-like reactivity in a CuIII2(μ-O)2 species. Chem. Eur. J., 2008, 14, 3535-3538.
  40. I.V. Korendovych, M. Cho, O.V. Makhlynets, P.L. Butler, R.J. Staples, E.V. Rybak-Akimova. Anion and carboxylic acid binding to monotopic and ditopic amidopyridine macrocycles. Journal of Organic Chemistry, 2008, 4771-4782. Featured on the cover of the July 2008 issue.
  41. J. E. McDonough, A. Mendiratta, J.J. Curley, G.C. Fortman, S. Fantasia, C.C. Cummins, E.V. Rybak-Akimova, S.P. Nolan, C.D. Hoff. Thermodynamic, kinetic, and computational study of heavier chalcogen (S, Se, and Te) terminal multiple bonds to molybdenum, carbon, and phosphorus. Inorg. Chem.,2008, 47, 2133-2141.
  42. G.T. Rowe, E.V. Rybak-Akimova, J.P. Caradonna. Unraveling the reactive species of a functional non-heme iron monooxygenase model using stopped-flow UV-vis spectroscopy. Inorg. Chem., 2007, 46, 10594-10606.
  43. J.P. Wikstrom, A.Y. Nazarenko, W.M. Reiff, E.V. Rybak-Akimova. Synthesis and characterization of tetrakis(µ-hydroxo)tetrakis(2,2'-dipicolylamine)tetranickel perchlorate, a nickel-hydroxy cubane complex. Inorg. Chim. Acta, 2007, 360, 3733-3740.
  44. I.V. Korendovych, S.V. Kryatov, E.V. Rybak-Akimova. Dioxygen activation at non-heme iron: Insights from rapid kinetic studies. Acc. Chem. Res., 2007, 40, 510-521.
  45. A. Company, L. Gomez, R. Mas-Balleste, I.V. Korendovych, X. Ribas, A. Poater, T. Parella, X. Fontrodona, J. Benet-Buchholz, M. Sola, L. Que, Jr., E.V. Rybak-Akimova, M. Costas. Fast O2 binding at dicopper complexes containing Schiff base dinucleating ligands. Inorg. Chem., 2007, 46, 4997-5012.
  46. I.V. Korendovych, O.P. Kryatova, W.M. Reiff, E.V. Rybak-Akimova. Iron(II) complexes with amide-containing macrocycles as non-heme porphyrin analogues. Inorg. Chem., 2007, 46, 4197-4211.
  47. S. Taktak, W. Ye, A.M. Herrera, E.V. Rybak-Akimova. Synthesis and catalytic properties in olefin epoxidation of novel iron(II) complexes with pyridine-containing macrocycles bearing an aminopropyl pendant arm. Inorg. Chem., 2007, 46, 2929-2942.
  48. J.D. Soper, S.V. Kryatov, E.V. Rybak-Akimova, D.G. Nocera. Proton-directed redox control of O-O bond activation by heme hydroperoxidase models. J. Am. Chem. Soc.,2007, 129, 5069-5075.
  49. I.V. Korendovych, R.R. Roesner, E.V. Rybak-Akimova. Molecular recognition of neutral and charged guests using metallomacrocyclic hosts. Advances in Inorganic Chemistry (invited review), Academic Press: Amsterdam, 2007. Edited by R. van Eldik and C. Bowman-James. Volume 59: Template Effects and Molecular Organization, pp. 109-173.
  50. S. Taktak, S. V. Kryatov, T. E. Haas, E.V. Rybak-Akimova. Diiron(III) oxo-bridged complexes with BPMEN and additional monodentate or bidentate ligands: Synthesis and reactivity in olefin epoxidation with H2O2. J. Mol. Cat. A, 2006, 259(1-2), 24-34.
  51. S.Y. Liu, J.D. Soper, J.Y. Yang, E.V. Rybak-Akimova, D.G. Nocera. Mechanistic studies of hangman salophen-mediated activation of O-O bonds. Inorg. Chem., 2006, 45, 7572-7574.
  52. I.V. Korendovych, M. Cho, P.L. Butler, R.J. Staples, E.V. Rybak-Akimova. Anion binding to monotopic and ditopic macrocyclic amides. Org. Lett., 2006, 8, 3171-3174.
  53. J.E. McDonough, J.J. Weir, K. Sukcharoenphon, C.D. Hoff, O.P. Kryatova, E.V. Rybak-Akimova, B.L. Scott, G.J. Kubas, A. Mendiratta, C.C. Cummins. Comparison of thermodynamic and kinetic aspects of oxidative addition of PhE-EPh (E = S, Se, Te) to Mo(CO)3(PR3)2, W(CO)3(PR3)2, and Mo(N[tBu]Ar)3 complexes. The role of oxidation state and ancillary ligands in metal complex induced chalcogenyl radical generation. J. Am. Chem. Soc., 2006, 128, 10295-10303.
  54. A. Company, D. Lamata, A. Poater, M. Solà, E.V. Rybak-Akimova, L. Que, Jr., X. Fontrodona, T. Parella, A. Llobet, M. Costas. O2 chemistry of dicopper complexes with alkyltriamine ligands. Comparing synergistic effects on O2 binding. Inorg. Chem., 2006, 45, 2539-2541.
  55. M.P. Jensen, E.L. Que, X. Shan, E.V. Rybak-Akimova, L. Que, Jr. Spectroscopic and kinetic studies of the reaction of [CuI(6-PhTPA)]+ with O2. Dalton Trans., 2006, 3523-3527.
  56. A. Mendiratta, C.C. Cummins, O.P. Kryatova, E.V. Rybak-Akimova, J.E. McDonough, C.D. Hoff. Benzonitrile extrusion from Mo(IV) ketimide complexes obtained via radical C-E (E = O, S, Se) bond formation: Toward a new nitrogen atom transfer reaction. J. Am. Chem. Soc., 2006, 128, 4881-4891.
  57. I.V. Korendovych, O.V. Makhlynets, S.K. Buzak, M.M. Flook, S.V. Kryatov, T.E. Haas, E.V. Rybak-Akimova. (1R,2R)-(+)-4,4'-Di-tert-butyl-2,2'-[1,2-diphenylethane-1,2-diylbis(nitrilomethylidyne)]diphenol. Acta Cryst., 2006, E62, o1240-o1242.
  58. F.H. Stephens, M.J.A. Johnson, C.C. Cummins, O.P. Kryatova, S.V. Kryatov, E.V. Rybak-Akimova, J.E. McDonough, C.D. Hoff. Mechanism of white phosphorous activation by three-coordinate molybdenum(III) complexes: A thermochemical, kinetic, and quantum chemical investigation. J. Am. Chem. Soc., 2005, 127, 15191-15200.
  59. I.V. Korendovych, S.V. Kryatov, W.M. Reiff, E.V. Rybak-Akimova. Diiron(II) µ-aqua-µ-hydroxo model for non-heme iron sites in proteins. Inorg. Chem., 2005, 44, 8656-8658.
  60. S. Taktak, M. Flook, B.M. Foxman, L. Que, Jr., E.V. Rybak-Akimova. ortho-Hydroxylation of benzoic acids with hydrogen peroxide at a non-heme iron center. Chem. Commun.,2005, 42, 5301-5303.
  61. S.V. Kryatov, E.V. Rybak-Akimova, S. Schindler. Kinetics and mechanisms of formation and reactivity of non-heme iron oxygen intermediates. Chem. Rev., 2005, 105, 2175-2226. Invited review for a special issue on inorganic and bioinorganic reaction mechanisms.
  62. J.E. McDonough, J.J. Weir, M.J. Carlson, C.D. Hoff, O.P. Kryatova, E.V. Rybak-Akimova, C.R. Clough, C.C. Cummins. Solution calorimetric and stopped-flow kinetic studies of the reaction of Cr(CO)3C5Me5 with PhSe-SePh and PhTe-TePh. Experimental and theoretical estimates of the Se-Se, Te-Te, H-Se, and H-Te bond strengths. Inorg. Chem., 2005, 44, 3127-3136.
  63. S.V. Kryatov, S. Taktak, I.V. Korendovych, E.V. Rybak-Akimova, J. Kaizer, S. Torelli, X. Shan, S. Mandal, V. MacMurdo, A.M. i Payeras, L. Que, Jr. Dioxygen binding to complexes with FeII2(µ-OH)2 cores: Steric control of activation barriers and O2-adduct formation. Inorg. Chem., 2005, 44, 85-99.
  64. N.W. Aboelella, S.V. Kryatov, B.F. Gherman, W.W. Brennessel, V.G. Young, Jr., R. Sarangi, E.V. Rybak-Akimova, K.O. Hodgson, B. Hedman, E.I. Solomon, C.J. Cramer, W.B. Tolman. Dioxygen activation at a single copper site: Structure, bonding, and mechanism of formation of 1:1 Cu:O2 adducts. J. Am. Chem. Soc., 2004, 126, 16896-16911.
  65. J.J. Wang, O.P. Kryatova, E.V. Rybak-Akimova, R.H. Holm. Comparative kinetics and mechanism of oxygen and sulfur atom transfer reactions mediated by bis(dithiolene) complexes of molybdenum and tungsten. Inorg. Chem., 2004, 43, 8092-8101.
  66. S. Taktak, S.V. Kryatov, E.V. Rybak-Akimova. Reactivity of a (µ-oxo)(µ-hydroxo)diiron(III) diamond core with water, urea, substituted ureas, and acetamide. Inorg. Chem., 2004, 43,7196-7209.
  67. I.V. Korendovych, R.J. Staples, W.M. Reiff, E.V. Rybak-Akimova. A new high-spin iron(III) complex with a pentadentate macrocyclic amidopyridine ligand: A change from slow single-ion paramagnetic relaxation to long-range antiferromagnetic order in a hydrogen-bonded network. Inorg. Chem.,2004, 43, 3930-3941.
  68. F.H. Stephens, J.S. Figueroa, C.C. Cummins, O.P. Kryatova, S.V. Kryatov, E.V. Rybak-Akimova, J.E. McDonough, C.D. Hoff. Small-molecule activation by molybdaziridine hydride complexes: Mechanistic sequence of the small-molecule binding and molybdaziridine ring-opening steps. Organometallics, 2004, 23, 3126-3138.
  69.  O.P. Kryatova, I.V.Korendovych, E.V. Rybak-Akimova. Complexes of benzo-15-crown-5 with protonated primary amines and diamines. Tetrahedron, 2004, 60, 4579-4588.
  70. S.V. Kryatov, F.A. Chavez, A.M. Reynolds, E.V. Rybak-Akimova, L. Que, Jr., W.B. Tolman. Mechanistic studies on the formation and reactivity of dioxygen adducts of diiron complexes supported by sterically hindered carboxylates. Inorg. Chem.,2004, 43, 2141-2150.
  71. I.V. Korendovych, E.V. Rybak-Akimova. Chloro{2,2'-[(1S,2S)-1,2-diphenyl-1,2-ethanediylbis(nitrilomethylidyne)]-diphenolato-κ4O,N,N',O'}(ethanol-κO)manganese(III). Acta Cryst., 2004, C60, m82-m84.
  72. A. Mendiratta, C.C. Cummins, O.P. Kryatova, E. V. Rybak-Akimova, J. E. McDonough, C.D. Hoff. Molybdenum chalcogenobenzimidato complexes: Radical synthesis and nitrile extrusion via β-EPh (E = S, Se, and Te) elimination. Inorg. Chem., 2003, 42(26), 8621-8623.
  73. E.V. Basiuk (Golovataya-Dzhymbeeva), V.A. Basiuk, E.V. Rybak-Akimova, D. Acosta-Najarro, I. Puente-Lee, J.M. Saniger. Hybrid materials based on single-walled carbon nanotubes and tetraazamacrocyclic compounds. The Electrochemical Society, Proceedings Volume 2003-15, Fullerenes Vol. 13: Fullerenes and Nanotubes: The Building Blocks of Next Generation Nanodevices (Proc. 203rd Meeting of The Electrochemical Society, April 27–May 2, 2003, Paris), D. M. Guldi, P. V. Kamat, and F. D’Souza (Eds.), pp. 375-382.
  74. M. Costas, C.W. Cady, S.V. Kryatov, M. Ray, M.J. Ryan, E.V. Rybak-Akimova, L. Que, Jr. Role of carboxylate bridges in modulating nonheme diiron(II)/O2 reactivity. Inorg. Chem., 2003, 42, 7519-7530.
  75. A.M. Herrera, G.V. Kalayda, J.S. Disch, J.P. Wikstrom, I.V. Korendovych, R.J. Staples, C.F. Campana, A.Y. Nazarenko, T.E. Haas, E.V. Rybak-Akimova. Reactions at the azomethine C=N bonds in the nickel(II) and copper(II) complexes of pyridine-containing Schiff base macrocyclic ligands. Dalton Trans., 2003, 4482-4492.
  76. J.S. Disch, R.J. Staples, T.E. Concolino, T.E. Haas, E.V. Rybak-Akimova. Nickel(II) cyclidenes with appended ethylpyridine receptor centers as molecular tweezers for dicarboxylic acids. Inorg. Chem.,2003, 42, 6749-6763.
  77. I.V. Korendovych, E.V. Rybak-Akimova. (-)-(1S,2S)-N,N’-Bis(salicylidene)-1,2-diphenyl-1,2-ethanediamine. Acta Cryst. E, 2003, 59, o1498-o1500.
  78. O.P. Kryatova, I.V. Korendovych, E.V. Rybak-Akimova. Proton-induced supramolecular dimerization of aminomethylbenzo-15-crown-5 accompanied by a covalent dimerization of cyanoborohydride anion. Tetrahedron Letters, 2003, 44, 4251-4255.
  79. S.V. Kryatov, E.V. Rybak-Akimova, F. Meyer, H. Pritzkow. A study of the equilibrium and kinetics of urea binding by a biomimetic dinickel(II) complex. Eur. J. Inorg. Chem., 2003, 1581-1590.
  80. A.M. Herrera, R.J. Staples, S.V. Kryatov, A.Y. Nazarenko, E.V. Rybak-Akimova. Nickel(II) and copper(II) complexes with pyridine-containing macrocycles bearing an aminopropyl pendant arm: Synthesis, characterization, and modifications of pendant amino group. Dalton Trans., 2003, 846-856.
  81. O.P. Kryatova, A.G. Kolchinski, E.V. Rybak-Akimova. Metal-containing ditopic receptors for molecular recognition of diammonium cations. Tetrahedron, 2003, 231-239.
  82. O.P. Kryatova, S.V. Kryatov, R.J. Staples, E.V. Rybak-Akimova. Stable supramolecular dimer of self-complementary benzo-18-crown-6 with a pendant arm. Chem. Commun., 2002, 3014-3015.
  83. E.V. Basiuk (Golovataya-Dzhumbeeva), E.V. Rybak-Akimova, V.A. Basiuk, D. Acosta-Najarro, J.M. Saniger. Adsorption modification of single-walled carbon nanotubes with tetraazaannulene macrocyclic complexes. Nano Letters, 2002, 2, 1249-1252.
  84. O.P. Kryatova, A.G. Kolchinski, E.V. Rybak-Akimova. Molecular tweezers for dicarboxylic acids based on a saddle-shaped metallomacrocyclic platform. J. Inclusion Phenom. Macrocyclic Chem., 2002, 42, 251-260.
  85. F.A. Chavez, R.Y.N. Ho, M. Pink, V.G. Young, Jr., S.V. Kryatov, E.V. Rybak-Akimova, H.P. Andres, E. Munck, L. Que, Jr., W.B. Tolman. Unusual peroxo intermediates in the reaction of dioxygen with carboxylate-bridged diiron(II,II) paddlewheel complexes. Angew. Chem. Int. Ed. Engl., 2002, 41, 149-152.
  86. S.V. Kryatov, B.S. Mohanraj, V.V. Tarasov, O.P Kryatova, E.V. Rybak-Akimova, B. Nuthakki, J.F. Rusling, R.J. Staples, A.Y. Nazarenko. Nickel(II) complexes with pentadentate aminopyridine ligands (PyCH2CH2)2NCH2CH2N(R)CH2CH2Py (R = H, Me): Synthesis, structure, electrochemistry, and reduction to nickel(I) species. Inorg. Chem., 2002, 41, 923-930.
  87. Y. Nazarenko, P.D. Robinson, R. M. Wilson, A. G. Kolchinski, J.S. Disch, E.V. Rybak-Akimova. Structural consequences of deacylation of cyclidenes under acidic and basic conditions. J. Inclusion Phenom. Macrocyclic Chem., 2002, 42, 83-87.
  88. E.V. Rybak-Akimova. Macrocyclic metallocomplexes in multipoint recognition of neutral and anionic guests. Rev. Inorg. Chem., 2001, 21, 207-298. Invited review for a special issue on chemistry of macrocyclic complexes.
  89. E.V. Rybak-Akimova, A.Y. Nazarenko, L. Chen, P.W. Krieger, A.M. Herrera, V.V. Tarasov, P. D.Robinson. Synthesis, characterization, redox properties, and representative X-ray structures of four- and five-coordinate copper(II) complexes with polydentate aminopyridine ligands. Inorg. Chim. Acta, 2001, 324, 1-15. Invited paper for a special issue on copper chemistry.
  90. J-P. F. Cherry, A.R. Johnson, L.M. Baraldo, Y-C. Tsai, C.C. Cummins, S.V. Kryatov, E.V. Rybak-Akimova, K.B. Capps, C.D. Hoff, C.M. Haar, S.P. Nolan. On the origin of selective nitrous oxide N-N bond cleavage by three-coordinate molybdenum(III) complexes. J. Am. Chem. Soc., 2001, 123, 7271-7286.
  91. E.V. Rybak-Akimova, S.V. Kryatov, A.M. Herrera. Peroxide activation by dinuclear and mononuclear iron model complexes: Which intermediates are reactive? J. Inorg. Biochem., 2001, 86, 414.
  92. S.V. Kryatov, A.Y. Nazarenko, M.B. Smith, E.V. Rybak-Akimova. Condensation of acetonitrile into N-acetimidoylacetamidine promoted by a dinuclear nickel(II) complex. Chem. Commun., 2001, 1174-1175.
  93. S.V. Kryatov, E.V. Rybak-Akimova, V.L. MacMurdo, L. Que, Jr. A mechanistic study of the reaction between a diiron(II) complex [FeII2(µ-OH)2(6-Me3TPA)2]2+ and O2 to form a diiron(III) peroxo complex. Inorg. Chem., 2001, 40, 2220-2228.
  94. S.V. Kryatov, A.Y. Nazarenko, P.D. Robinson, E.V. Rybak-Akimova. A dinuclear iron(III) complex with a bridging urea anion: Implications for the urease mechanism. Chem. Commun., 2000, 921-922.
  95. E.V. Rybak-Akimova, K. Kuczera. Ligand binding inside the cavities of lacunar and saddle-shaped cyclidene complexes: Molecular mechanics and molecular dynamics studies. Inorg. Chem., 2000, 39, 2462-2472.
  96. S.V. Kryatov, E.V. Rybak-Akimova. A kinetic study of the formation of a model high-valent diiron non-heme complex, [FeIIIFeIV(µ-O)2(tpa)2]3+ (tpa = tris-(2-pyridylmethyl)amine), by cryogenic stopped-flow technique. J. Chem. Soc. Dalton Trans., 1999, 19, 3335-3336.
  97. E.V. Rybak-Akimova, A.Y. Nazarenko. S.S. Silchenko. Unusual ligand isomerization dictated by coordination requirements of the metal ion: A double bond shift in Cu(II) assisted template condensation between diacetylpyridine and a tripodal tetramine. Inorg. Chem.,1999, 38, 2974-2980.
  98. E.V. Rybak-Akimova, K. Kuczera, G.S. Jas, Y. Deng, D.H. Busch. Molecular shape and solvation of the lacunar, saddle-shaped, and planar metal cyclidene complexes: Molecular dynamics studies. Inorg. Chem.,1999, 38, 3423-3434.
  99. G. Gonzalez, M.A. Gilles-Gonzalez, E.V. Rybak-Akimova, M. Buchalova, D.H. Busch. Mechanisms of autoxidation of the oxygen sensor FixL and Aplysia myoglobin: Implications for oxygen binding heme proteins. Biochemistry, 1998, 37, 10188-10194.
  100. N.W. Alcock, H.J. Clase, S. Siltchenko, E.V. Rybak-Akimova, D.H. Busch. Chloro(N,N’,N’’-trimethyl-1,5,9-triazacyclododecane-κ3N)zinc(II) hexafluorophosphate. Acta Cryst., 1998, C54, 338-340.
  101. E.V. Rybak-Akimova, K. Marek, M. Masarwa, D.H. Busch. The dynamics of formation of the O2–Co(II) bond in the cobalt(II) cyclidene complexes. Inorg. Chim. Acta (Halpern’s Issue), 1998, 270, 151-161.
  102. E.V. Rybak-Akimova, N.W. Alcock, D.H. Busch. Dicompartmental ligands with hexa- and tetradentate coordination sites: One-step synthesis of ligands and metal complexes, and their X-ray structure analysis. Inorg. Chem., 1998, 37, 1563-1574.
  103. D.H. Busch, R.A. Roesner, T.L. Allison II, E.V. Rybak-Akimova, L. Chung. Determination of the compressibility of liquid phase host-guest systems. J. Inclusion Phenom. Mol. Recogn. Chem., 1998, 30, 185-196.
  104. N.W. Alcock, E.V. Rybak-Akimova, D.H. Busch. A cis-ocathedral dichloro complex of Fe(III) with a tetradentate diamino-dipyridine ligand. Acta Cryst., 1997, C53, 1385-1387.
  105. E.V. Rybak-Akimova, W. Otto, P. Deardorf, R.A. Roesner, D.H. Busch. Kinetics and equilibrium of oxygen binding to a vacant site in cobalt(II) complexes with pentadentate ligands. Inorg. Chem., 1997, 36, 2746-2753.
  106. A.G. Kolchinski, B. Korybut-Daskiewisz, E.V. Rybak-Akimova, D.H. Busch, N.W. Alcock, H.J.Clase. Unsubstituted cyclidenes - a novel family of lacunar dioxygen carriers with enhanced stability toward autoxidation: Synthesis, characterization, and a representative X-ray structure. J. Am. Chem. Soc., 1997, 119, 4160-4171.
  107. E.V. Rybak-Akimova, M. Masarwa, K. Marek, P.R. Warburton, D.H. Busch. Dynamics of dioxygen binding to vacant cobalt(II) sites in lacunar cyclidene complexes: Barrier-free oxygenation. Chem. Commun., 1996, 1451-1452.
  108. E.V. Rybak-Akimova, Y.D. Lampeka. A new ditopic receptor containing tetraazamacrocyclic and crown ether fragments. Synthesis, spectral characteristics, and redox behavior. Supramol. Chem., 1995, 4, 297-304.
  109. P.E. Strizhak, K.B. Yatsimirskii, E.V. Rybak-Akimova. Autooscillations and deterministic chaos in a modeling of biochemical oxidation processes. Zh. Russ. Chem. Soc. (Mendeleev Soc.), 1995, 39, N1, 89-94.
  110. E.V. Rybak-Akimova, Y.D. Lampeka. Synthesis and characteristics of the redox behavior of a ditopic compound containing tetraaza macrocyclic and crown ether fragments. Theoret. Exper. Khim., 1992, 28, 162-167. (Engl. transl.: Theoret. Exper. Chem., 142-145).
  111. K.B. Yatsimirskii, L.N. Zakrevskaya, P.E. Strizhak, E.V. Rybak-Akimova. New oscillation reactions and pattern formation in dioxygen systems. Chem. Phys. Lett., 1991, 186, 15-18.
  112. L.N. Zakrevskaya, P.E. Strizhak, E.V. Rybak-Akimova. Formation of spatial structures in two-phase chemical systems with diffusion. Zh. Obshch. Khim., 1991, 61, N12, 2647-2653. (Engl. transl.: Russian Journal of General Chemistry, 2453-2458).
  113. K.B. Yatsimirskii, E.V. Rybak-Akimova, P.R. Bonchev, E. Zhecheva, V. Rusanov, M. Miteva, N. Iordanov. The reaction of a macrocyclic complex of iron(II) with nitrogen(II) oxide and the characteristics of the compounds [Fe(TAAB)(CH3CN)2](BF4)2 and [Fe(TAAB)(CH3CN)(NO)](BF4)2. Zh. Neorg. Khim., 1990, 35, N12, 3131-3138. (Engl. transl.: Russian Journal of Inorganic Chemistry, 1778-1782).
  114. K.B. Yatsimirskii, E.V. Rybak-Akimova, G.G. Talanova. Synthesis and structure of iron(III) complexes with macrocyclic polyether. Transactions of the Academy of Sciences of the Ukrainian SSR, Phys.-Mat. and Technical Sciences, Ser. B, 1989, N4, 50-53.
  115. K.B. Yatsimirskii, D.V. Matyushov, L.N. Zakrevskaya, E.V. Rybak-Akimova, L.P. Tikhonova. Conditions for formation of stationary spatial structures in oxidation reactions of aromatic amines and phenols by atmospheric oxygen. Theoret. Exper. Khim., 1989, 25, N2, 183-191. (Engl. transl.: Theoret. Exper. Chem., 166-173).
  116. K.B. Yatsimirskii, L.N. Zakrevskaya, E.V. Rybak-Akimova. Oscillating reactions and formation of spatial structures in catalyzed oxidation of NADH, ascorbic acid and other low molecular weight biological substrates by oxygen. Dokl. AN SSSR, 1988, 300, N4, 866-870. (Engl. transl.: Doklady Chemistry, 169-172).
  117. K.B. Yatsimirskii, E.V. Rybak-Akimova. Stability of compounds of a tetraaza macrocyclic complex of iron(II) with axial ligands. Koord. Khim., 1986, 12, N9, 1237-1243. (Engl. transl.: Russian J. Coord. Chem., 723-728).
  118. K.B. Yatsimirskii, G.G. Talanova, E.V. Rybak-Akimova. Transport of iron(III) ions through a liquid membrane with the participation of macrocyclic ligands. Dokl. AN SSSR, 1986, 288, N3, 646-649. (Engl. transl.: Doklady Chemistry, 165-167).
  119. K.B. Yatsimirskii, E.V. Rybak-Akimova. Reaction of hydrogen peroxide with tetraazamacrocyclic complex of iron(II) in the presence of nitrogeneous bases. Theoret. Exper. Khim., 1986, 22, N3, 309-316. (Engl.transl.: Theoret. Exper. Chem.,291-298).
  120. K.B.Yatsimirskii, G.G.Talanova, E.V. Rybak-Akimova, A.S. Shtepanek, V.A. Popova. Interface transport of iron(III) chloride by means of macrocyclic ligands. Theoret. Exper. Khim., 1986, 22, N2, 174-180. (Engl. transl.: Theoret. Exper. Chem., 162-167).
  121. K.B. Yatsimirskii, V.V. Pavlishchuk, E.V. Rybak-Akimova. The preparation of complexes of zinc with tetraazamacrocyclic ligands and their analogues by the action of zinc amalgam on the copper complexes. Zh. Neorg. Khim., 1985, 30, N6, 1602-1604. (Engl. transl.: Russian Journal of Inorganic Chemistry, 912-914).
  122. V.V. Pavlishchuk, E.V. Rybak-Akimova, K.B. Yatsimirskii. Influence of substituents in the ligand on the properties of macrocyclic complexes of zinc. Theoter. Exper. Khim., 1985, 21, N4, 424-431. (Engl. transl.: Theoret. Exper. Chem., 404-410).
  123. K.B.Yatsimirskii, V.V. Pavlishchuk, E.V. Rybak-Akimova. Reaction kinetics in replacement of zinc ions by copper ions in complexes with cyclic and noncyclic tetramines. Theoter. Exper. Khim., 1985, 21, N2, 175-182. (Engl. transl.: Theoret. Exper. Chem., 168-174).